Complex carbonaceous matter in Tissint martian meteorites give insights into the diversity of organic geochemistry on Mars

Author:

Schmitt-Kopplin Philippe123ORCID,Matzka Marco3,Ruf Alexander145ORCID,Menez Benedicte6ORCID,Chennaoui Aoudjehane Hasnaa7ORCID,Harir Mourad3,Lucio Marianna3,Hertzog Jasmine13ORCID,Hertkorn Norbert3ORCID,Gougeon Régis D.8ORCID,Hoffmann Victor9,Hinman Nancy W.10,Ferrière Ludovic11ORCID,Greshake Ansgar12,Gabelica Zelimir13,Trif László14,Steele Andrew15

Affiliation:

1. Technische Universität München, Chair of Analytical Food Chemistry, Freising-Weihenstephan 85354, Germany.

2. Max Planck Institute for Extraterrestrial Physics, Center for Astrochemical Studies, Garching 85748, Germany.

3. Helmholtz München, Analytical BioGeoChemistry, Neuherberg 85764, Germany.

4. Excellence Cluster ORIGINS, Boltzmannstraße 2, Garching 85748, Germany.

5. Ludwig-Maximilians-University, Department of Chemistry and Pharmacy, Butenandtstr. 5-13, Munich 81377, Germany.

6. Université de Paris, Institut de Physique du Globe de Paris, CNRS - 1, rue Jussieu, Paris Cedex 05 75238, France.

7. Faculty of Sciences Ain Chock, GAIA Laboratory, Hassan II University of Casablanca, km 8 Route d’El Jadida, Casablanca 20150, Morocco.

8. UMR Procédés Alimentaires et Microbiologiques, Université de Bourgogne/AgroSupDijon, Institut Universitaire de la Vigne et du Vin Jules Guyot, Dijon 21000, France.

9. Faculty of Geosciences, Dep. Geo- and Environmental Sciences, LMU, Muenchen, Germany.

10. University of Montana, Missoula, MT 59812, USA.

11. Natural History Museum Vienna 1010, Austria.

12. Museum für Naturkunde Berlin, Berlin 10115, Germany.

13. Université de Haute Alsace, École Nationale Supérieure de Chimie de Mulhouse, F-68094 Mulhouse Cedex, France.

14. Research Centre for Natural Sciences, Institute of Materials and Environmental Chemistry, Budapest, Hungary.

15. Earth and Planetary Laboratory, Carnegie Institution for Science, 5251 Broad Branch Rd., Washington, DC 20015, USA.

Abstract

We report a huge organic diversity in the Tissint Mars meteorite and the sampling of several mineralogical lithologies, which revealed that the organic molecules were nonuniformly distributed in functionality and abundance. The range of organics in Tissint meteorite were abundant C 3-7 aliphatic branched carboxylic acids and aldehydes, olefins, and polyaromatics with and without heteroatoms in a homologous oxidation structural continuum. Organomagnesium compounds were extremely abundant in olivine macrocrystals and in the melt veins, reflecting specific organo-synsthesis processes in close interaction with the magnesium silicates and temperature stresses, as previously observed. The diverse chemistry and abundance in complex molecules reveal heterogeneity in organic speciation within the minerals grown in the martian mantle and crust that may have evolved over geological time.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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