Delocalized electron effect on single metal sites in ultrathin conjugated microporous polymer nanosheets for boosting CO 2 cycloaddition-Reference-Cited by-同舟云学术

Delocalized electron effect on single metal sites in ultrathin conjugated microporous polymer nanosheets for boosting CO 2 cycloaddition

Published:2020-04-24 Issue:17 Volume:6 Page:
ISSN:2375-2548
Container-title:Science Advances
language:en
Short-container-title:Sci. Adv.

Author:

Zhang Xiaofei¹²^ORCID,Liu Haitao³^ORCID,An Pengfei⁴^ORCID,Shi Yanan¹,Han Jianyu¹,Yang Zhongjie¹,Long Chang¹²^ORCID,Guo Jun¹,Zhao Shenlong¹,Zhao Kun¹,Yin Huajie¹^ORCID,Zheng Lirong⁴^ORCID,Zhang Binhao¹,Liu Xiaoping¹,Zhang Lijuan¹²,Li Guodong¹^ORCID,Tang Zhiyong¹²^ORCID

Affiliation:

1. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, P. R. China.

2. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150080, P. R. China.

3. Laboratory of Computational Physics, Institute of Applied Physics and Computational Mathematics, Beijing 100088, P. R. China.

4. Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, P. R. China.

Abstract

Electronic state of single metal sites in ultrathin CMP nanosheets is tuned via delocalized effect of conjugated skeletons.

Funder

National Natural Science Foundation of China

National Key Basic Research Program of China

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference46 articles.

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4. A Triazole-Containing Metal–Organic Framework as a Highly Effective and Substrate Size-Dependent Catalyst for CO2 Conversion

5. Bifunctional Porphyrin Catalysts for the Synthesis of Cyclic Carbonates from Epoxides and CO2: Structural Optimization and Mechanistic Study

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