Strong self-trapping by deformation potential limits photovoltaic performance in bismuth double perovskite

Author:

Wu Bo123ORCID,Ning Weihua4ORCID,Xu Qiang2,Manjappa Manukumara25ORCID,Feng Minjun2ORCID,Ye Senyun2ORCID,Fu Jianhui2ORCID,Lie Stener6ORCID,Yin Tingting2,Wang Feng4ORCID,Goh Teck Wee2ORCID,Harikesh Padinhare Cholakkal6ORCID,Tay Yong Kang Eugene2ORCID,Shen Ze Xiang257ORCID,Huang Fuqiang3,Singh Ranjan2ORCID,Zhou Guofu18ORCID,Gao Feng4ORCID,Sum Tze Chien2ORCID

Affiliation:

1. Guangdong Provincial Key Laboratory of Optical Information Materials and Technology and Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou 510006, P. R. China.

2. Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore.

3. CAS Key Laboratory of Materials for Energy Conversion and State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China.

4. Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping SE-581 83, Sweden.

5. Centre for Disruptive Photonic Technologies, The Photonics Institute, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore.

6. Energy Research Institute @ NTU (ERI@N), Research Techno Plaza, X-Frontier Block Level 5, 50 Nanyang Drive, Singapore 637553, Singapore.

7. CINTRA CNRS/NTU/Thales, UMI 3288, 50 Nanyang Drive, Singapore 637553, Singapore.

8. Shenzhen Guohua Optoelectronics Technology Co. Ltd., Shenzhen 518110, P. R. China.

Abstract

Bismuth double perovskite Cs 2 AgBiBr 6 strong electron–acoustic phonon interactions derail its photovoltaic aspirations.

Funder

National Research Foundation-Prime Minister’s office, Republic of Singapore

Ministry of Education - Singapore

Nanyang Technological University

National Natural Science Foundation of China

Knut och Alice Wallenbergs Stiftelse

Swedish Energy Agency

Guangdong Provincial Key Laboratory of Optical Information Materials and Technology

National Center for International Research on Green Optoelectronics

111 Project

Science and Technology Program of Guangzhou

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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