Paralyzed membrane: Current-driven synthesis of a metal-organic framework with sharpened propene/propane separation

Author:

Zhou Sheng1ORCID,Wei Yanying1ORCID,Li Libo1ORCID,Duan Yifan1,Hou Qianqian1ORCID,Zhang Lili1,Ding Liang-Xin1ORCID,Xue Jian1,Wang Haihui1,Caro Jürgen2ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China.

2. Institute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Callinstraße 3A, 30167 Hannover, Germany.

Abstract

ZIF-8 membranes with inborn-suppressed linker mobility sharpen molecular sieving with C 3 H 6 /C 3 H 8 separation factor above 300.

Funder

National Natural Science Foundation of China

Guangdong Natural Science Funds for Distinguished Young Scholar

NSFC-DFG

Natural Science Foundation of the Guangdong Province

1000 Talents Program of Chinese government

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference59 articles.

1. Seven chemical separations: To change the world: Purifying mixtures without using heat would lower global energy use, emissions and pollution—And open up new routes to resources;Sholl D. S.;Nature,2016

2. S. Robinson R. Jubin B. Choate Materials for Separation Technology: Energy and Emmision Reduction Opportunities. Washington DC: US Dept. of Energy (2005).

3. Enhanced ethylene separation and plasticization resistance in polymer membranes incorporating metal-organic framework nanocrystals;Bachman J. E.;Nat. Mater.,2016

4. A metal-organic framework–based splitter for separating propylene from propane

5. Propylene/propane separation by vacuum swing adsorption using 13X zeolite;Da Silva F. A.;AIChE J.,2001

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