Amorphization mechanism of SrIrO 3 electrocatalyst: How oxygen redox initiates ionic diffusion and structural reorganization

Author:

Wan Gang1ORCID,Freeland John W.2ORCID,Kloppenburg Jan3ORCID,Petretto Guido3ORCID,Nelson Jocienne N.4ORCID,Kuo Ding-Yuan5ORCID,Sun Cheng-Jun2,Wen Jianguo6ORCID,Diulus J. Trey7ORCID,Herman Gregory S.7ORCID,Dong Yongqi128,Kou Ronghui2,Sun Jingying9,Chen Shuo9ORCID,Shen Kyle M.410ORCID,Schlom Darrell G.51011ORCID,Rignanese Gian-Marco3ORCID,Hautier Geoffroy3ORCID,Fong Dillon D.1ORCID,Feng Zhenxing7ORCID,Zhou Hua2ORCID,Suntivich Jin510ORCID

Affiliation:

1. Materials Science Division, Argonne National Laboratory, Lemont, IL 60439, USA.

2. X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Lemont, IL 60439, USA.

3. Institute of Condensed Matter and Nanosciences, Université Catholique de Louvain, Chemin des Étoiles 8, B-1348 Louvain-la-Neuve, Belgium.

4. Laboratory of Atomic and Solid State Physics, Department of Physics, Cornell University, Ithaca, NY 14853, USA.

5. Department of Materials Science and Engineering, Cornell University, Ithaca, NY 14853, USA.

6. Center for Nanoscale Materials, Argonne National Laboratory, Lemont, IL 60439, USA.

7. School of Chemical, Biological, and Environmental Engineering, Oregon State University, Corvallis, OR 97331, USA.

8. National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026, China.

9. Department of Physics and the Texas Center for Superconductivity, University of Houston, Houston, TX 77204, USA.

10. Kavli Institute at Cornell for Nanoscale Science, Cornell University, Ithaca, NY 14853, USA.

11. Leibniz-Institut für Kristallzüchtung, Max-Born-Str. 2, 12489 Berlin, Germany.

Abstract

The transformation from crystalline SrIrO 3 to active amorphous iridium oxide electrocatalyst occurs via the lattice oxygen redox.

Funder

National Science Foundation

U.S. Department of Energy

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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