Role of iodine oxoacids in atmospheric aerosol nucleation

Author:

He Xu-Cheng1ORCID,Tham Yee Jun1ORCID,Dada Lubna1ORCID,Wang Mingyi2ORCID,Finkenzeller Henning3ORCID,Stolzenburg Dominik14ORCID,Iyer Siddharth5ORCID,Simon Mario6ORCID,Kürten Andreas6ORCID,Shen Jiali1,Rörup Birte1ORCID,Rissanen Matti5ORCID,Schobesberger Siegfried7ORCID,Baalbaki Rima1ORCID,Wang Dongyu S.8ORCID,Koenig Theodore K.3ORCID,Jokinen Tuija1ORCID,Sarnela Nina1ORCID,Beck Lisa J.1ORCID,Almeida João9ORCID,Amanatidis Stavros10ORCID,Amorim António11ORCID,Ataei Farnoush12,Baccarini Andrea8ORCID,Bertozzi Barbara13ORCID,Bianchi Federico1ORCID,Brilke Sophia4,Caudillo Lucía6,Chen Dexian2ORCID,Chiu Randall3ORCID,Chu Biwu1ORCID,Dias António11ORCID,Ding Aijun1415ORCID,Dommen Josef8ORCID,Duplissy Jonathan116ORCID,El Haddad Imad8ORCID,Gonzalez Carracedo Loïc4,Granzin Manuel6,Hansel Armin1718ORCID,Heinritzi Martin6ORCID,Hofbauer Victoria2ORCID,Junninen Heikki119ORCID,Kangasluoma Juha1ORCID,Kemppainen Deniz1ORCID,Kim Changhyuk1020ORCID,Kong Weimeng10ORCID,Krechmer Jordan E.21ORCID,Kvashin Aleksander22ORCID,Laitinen Totti1,Lamkaddam Houssni8ORCID,Lee Chuan Ping8ORCID,Lehtipalo Katrianne123ORCID,Leiminger Markus1718ORCID,Li Zijun7ORCID,Makhmutov Vladimir22ORCID,Manninen Hanna E.9ORCID,Marie Guillaume6ORCID,Marten Ruby8ORCID,Mathot Serge9,Mauldin Roy L.24ORCID,Mentler Bernhard17ORCID,Möhler Ottmar13,Müller Tatjana6ORCID,Nie Wei1415ORCID,Onnela Antti9ORCID,Petäjä Tuukka1ORCID,Pfeifer Joschka9,Philippov Maxim22ORCID,Ranjithkumar Ananth25ORCID,Saiz-Lopez Alfonso26ORCID,Salma Imre27ORCID,Scholz Wiebke1718ORCID,Schuchmann Simone28,Schulze Benjamin10ORCID,Steiner Gerhard17,Stozhkov Yuri22,Tauber Christian4ORCID,Tomé António29ORCID,Thakur Roseline C.1ORCID,Väisänen Olli7,Vazquez-Pufleau Miguel4ORCID,Wagner Andrea C.36ORCID,Wang Yonghong1,Weber Stefan K.9ORCID,Winkler Paul M.4,Wu Yusheng1,Xiao Mao8ORCID,Yan Chao1ORCID,Ye Qing2ORCID,Ylisirniö Arttu7ORCID,Zauner-Wieczorek Marcel6ORCID,Zha Qiaozhi1ORCID,Zhou Putian1ORCID,Flagan Richard C.10ORCID,Curtius Joachim6ORCID,Baltensperger Urs8ORCID,Kulmala Markku1141630ORCID,Kerminen Veli-Matti1ORCID,Kurtén Theo31,Donahue Neil M.2323334ORCID,Volkamer Rainer3ORCID,Kirkby Jasper69ORCID,Worsnop Douglas R.121ORCID,Sipilä Mikko1ORCID

Affiliation:

1. Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland.

2. Center for Atmospheric Particle Studies, Carnegie Mellon University, Pittsburgh, PA 15213, USA.

3. Department of Chemistry and Cooperative Institute for Research in the Environmental Sciences, University of Colorado Boulder, Boulder, CO 80309, USA.

4. Faculty of Physics, University of Vienna, 1090 Vienna, Austria.

5. Aerosol Physics Laboratory, Physics Unit, Faculty of Engineering and Natural Sciences, Tampere University, 33014 Tampere, Finland.

6. Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany.

7. Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland.

8. Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, CH-5232 Villigen, Switzerland.

9. CERN, the European Organization for Nuclear Research, CH-1211 Geneva 23, Switzerland.

10. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA.

11. CENTRA and Faculdade de Ciências da Universidade de Lisboa, 1749-016 Lisboa, Portugal.

12. Leibniz Institute for Tropospheric Research, 04318 Leipzig, Germany.

13. Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen, Germany.

14. Joint International Research Laboratory of Atmospheric and Earth System Sciences, School of Atmospheric Sciences, Nanjing University, Nanjing 210023, China.

15. Jiangsu Provincial Collaborative Innovation Center of Climate Change, Nanjing 210023, China.

16. Helsinki Institute of Physics, University of Helsinki, 00014 Helsinki, Finland.

17. Institute of Ion Physics and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria.

18. Ionicon Analytik Ges.m.b.H., 6020 Innsbruck, Austria.

19. Institute of Physics, University of Tartu, 50411 Tartu, Estonia.

20. School of Civil and Environmental Engineering, Pusan National University, Busan 46241, Republic of Korea.

21. Aerodyne Research, Inc., Billerica, MA 01821, USA.

22. P.N. Lebedev Physical Institute of the Russian Academy of Sciences, 119991 Moscow, Russia.

23. Finnish Meteorological Institute, 00560 Helsinki, Finland.

24. Department of Atmospheric and Oceanic Sciences, University of Colorado, Boulder, CO 80309, USA.

25. School of Earth and Environment, University of Leeds, Leeds LS2 9JT, UK.

26. Department of Atmospheric Chemistry and Climate, Institute of Physical Chemistry Rocasolano, CSIC, 28006 Madrid, Spain.

27. Institute of Chemistry, Eötvös University, H-1117 Budapest, Hungary.

28. Institute of Physics, Johannes Gutenberg University Mainz, 55128 Mainz, Germany.

29. Institute Infante Dom Luíz, University of Beira Interior, 6201-001 Covilhã, Portugal.

30. Aerosol and Haze Laboratory, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China.

31. Department of Chemistry, University of Helsinki, University of Helsinki, 00014 Helsinki, Finland.

32. Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, USA.

33. Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213, USA.

34. Department of Engineering and Public Policy, Carnegie Mellon University, Pittsburgh, PA 15213, USA.

Abstract

Faster than expected Iodine species are one of only a handful of atmospheric vapors known to make new aerosol particles, which play a central role in controlling the radiative forcing of climate. He et al. report experimental evidence from the CERN Cosmics Leaving Outdoor Droplets, or CLOUD, chamber demonstrating that iodic acid and iodous acid rapidly form new particles and can compete with sulfuric acid in pristine regions. Science , this issue p. 589

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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