Affiliation:
1. Chemical Physics, Chemical Center, Post Office Box 124, S-22100 Lund, Sweden.
Abstract
This report presents positive infrared spectroscopic identification of H
2
O
3
, a higher oxide of hydrogen of importance for the understanding of the chain formation ability of atomic oxygen and a possible intermediate in hydrogen oxygen radical chemistry. All fundamental vibrations of H
2
O
3
, isolated in an argon matrix, have been observed. In addition, several bands of HDO
3
, D
2
O
3
, and H
2
16
O
2
18
O have been measured. One particular mode, the antisymetric O–O stretch at 776 cm
−1
, should be observable even in the presence of high water concentrations.
Publisher
American Association for the Advancement of Science (AAAS)
Cited by
74 articles.
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