Normal Modes and Density of States of Disordered Colloidal Solids

Author:

Kaya D.1,Green N. L.2,Maloney C. E.3,Islam M. F.12

Affiliation:

1. Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213–3890, USA.

2. Department of Chemical Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213–3890, USA.

3. Department of Civil and Environmental Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213–3890, USA.

Abstract

Measuring Motion Within a solid, atoms vibrate about their mean position in a series of frequencies known as the normal modes, which relate to the thermal and mechanical transport properties of the material. D. Kaya et al. (p. 656 ) used video microscopy to observe the motion of colloidal crystals made from microgel particles. The colloidal particles varied slightly in their properties, allowing the behavior of disordered materials to be probed. Long-wavelength plane-wave modes were observed, characteristic of perfect crystals, and a conventional elastic behavior, modified by short-wavelength features, was also observed, in spite of the disorder of the colloidal crystals. The analysis method will allow studies on the effects of different types of disorder on the structure of the normal modes and the elasticity in a range of material systems.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference30 articles.

1. N. W. Ashcroft N. D. Mermin Solid State Physics (Saunders College Philadelphia 1976).

2. S. R. Elliott Physics of Amorphous Materials (Longmans New York 1990).

3. The theory and properties of randomly disordered crystals and related physical systems

4. Origin of the Boson Peak in Systems with Lattice Disorder

5. Harmonic Vibrational Excitations in Disordered Solids and the “Boson Peak”

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