The Water Dipole Moment in Water Clusters-Reference-Cited by-同舟云学术

The Water Dipole Moment in Water Clusters

Published:1997-02-07 Issue:5301 Volume:275 Page:814-817
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Gregory J. K.¹,Clary D. C.²,Liu K.²,Brown M. G.³,Saykally R. J.³

Affiliation:

1. J. K. Gregory, Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK.

2. D. C. Clary, Department of Chemistry, University College London, London WC1H OAJ, UK.

3. K. Liu, M. G. Brown, R. J. Saykally, Department of Chemistry, University of California, Berkeley, CA 94720, USA.

Abstract

The average dipole moment of a water molecule in the condensed phase is enhanced by around 40 percent relative to that of an isolated monomer. This enhancement results from the large polarization caused by the electric field induced by surrounding monomers. A quantitative molecular description of this polarization is essential for modeling aqueous solvation phenomena. This combined theoretical and experimental study of dipole moments in small water clusters provides such a description and also gives insights into the structure of liquid water.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference47 articles.

1. Pugliano N., Saykally R. J., J. Chem. Phys. 96, 1832 (1992);

2. Measurement of quantum tunneling between chiral isomers of the cyclic water trimer

3. Cruzan J. D., et al., ibid. 271, 59 (1996);

4. Liu K. , Brown M. G. , Cruzan J. D. , Saykally R. J., ibid., p. 62.

5. Kim K. S., Dupuis M., Lie G. C., Clementi E., Chem. Phys. Lett. 131, 451 (1986);

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