Uniform patchy and hollow rectangular platelet micelles from crystallizable polymer blends

Author:

Qiu Huibin1,Gao Yang1,Boott Charlotte E.1,Gould Oliver E. C.1,Harniman Robert L.1,Miles Mervyn J.2,Webb Stephen E. D.3,Winnik Mitchell A.4,Manners Ian1

Affiliation:

1. School of Chemistry, University of Bristol, Bristol BS8 1TS, UK.

2. School of Physics, University of Bristol, Bristol BS8 1TL, UK.

3. Central Laser Facility, Science and Technology Facilities Council, Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot OX11 0QX, UK.

4. Department of Chemistry, University of Toronto, Toronto, Ontario, M5S 3H6, Canada.

Abstract

Growing patterned rectangular objects The growth of patterned objects usually requires a template to aid the positioning of multiple materials. Qiu et al. used the seeded growth of a crystallizable block copolymer and a homopolymer to produce highly uniform rectangular structures (see the Perspective by Ballauff). Chemical etching, or dissolution, of uncross-linked regions of the rectangular structures produced perforated platelet micelles. The sequential addition of different blends and cross-linking/dissolution strategies allowed the formation of well-defined hollow rectangular micelles, which can be functionalized in a variety of ways. Science , this issue p. 697 ; see also p. 656

Funder

European Research Council

Engineering and Physical Sciences Research Council (EPSRC)

Natural Sciences and Engineering Research Council of Canada

Medical Research Council

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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