A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst-Reference-Cited by-同舟云学术

A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst

Published:2012-10-05 Issue:6103 Volume:338 Page:90-94
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Costentin Cyrille¹,Drouet Samuel¹,Robert Marc¹,Savéant Jean-Michel¹

Affiliation:

1. Université Paris Diderot, Sorbonne Paris Cité, Laboratoire d’Electrochimie Moléculaire, Unité Mixte de Recherche Université–CNRS no. 7591, Bâtiment Lavoisier, 15 Rue Jean de Baïf, 75205 Paris Cedex 13, France.

Abstract

Lending a Hand to CO 2 Reduction Although plants and microbes have been reducing CO 2 with ease for millennia, people still find it extremely challenging. A cost-effective synthetic scheme for transforming CO 2 into fuels and commodity chemicals would be a double boon, lowering atmospheric concentration of the greenhouse gas while supplementing (and perhaps ultimately replacing) dwindling petroleum feedstocks. Toward this end, Costentin et al. (p. 90 ) show that an iron catalyst for the electrochemical reduction of CO 2 to CO gets an efficiency boost from phenol substituents appended to the ligand framework.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference38 articles.

1. Standard potential and kinetic parameters of the electrochemical reduction of carbon dioxide in dimethylformamide

2. Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

3. Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels

4. Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation

5. Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins. Synergistic Effect of Lewis Acid Cations

Cited by 1131 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Improving CO2 electroconversion by customizing the hydroxyl microenvironment around a semi-open Co-N2O2 configuration;Journal of Colloid and Interface Science;2025-01

2. Ferrocenyl PNNP Ligands-Controlled Chromium Complex-Catalyzed Photocatalytic Reduction of CO₂ to Formic Acid;Journal of the American Chemical Society;2024-09-06

3. Co-capture and resource recovery of ammonia and carbon dioxide in microbial electrolysis system with an assisted carbon capacitor chamber;Journal of Cleaner Production;2024-09

4. Mechanistic insight into electrocatalytic CO2 reduction to formate by the iron(I) porphyrin complex: A DFT study;Molecular Catalysis;2024-09

5. Toward an informative comparison of heterogeneous, synthetic, and biological electrocatalysis in energy conversion;Chem Catalysis;2024-09