Design of higher valency in covalent organic frameworks-Reference-Cited by-同舟云学术

Design of higher valency in covalent organic frameworks

Published:2020-10-23 Issue:6515 Volume:370 Page:
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Gropp Cornelius¹²^ORCID,Ma Tianqiong¹²^ORCID,Hanikel Nikita¹²^ORCID,Yaghi Omar M.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of California–Berkeley, Berkeley, CA 94720, USA.

2. Kavli Energy Nanoscience Institute at UC Berkeley, Berkeley, CA 94720, USA.

Abstract

Higher-valency ligands for COFs Metal-organic frameworks (MOFs) have exhibited more extensive connectivity (valency) and topological diversity than covalent organic frameworks (COFs), mainly because MOF linkers can connect from 3 to 24 discrete units or even infinity for one-dimensional rods. For COFs, linkers generally have a valency of 3 or 4 that reflect the valency of organic carbon. Gropp et al. created cubane-like linkers from 1,4-boronophenylphosphonic acid that could condense to make COFs with a valency of 8 or, by adding acid, could form large, single crystals with an infinite-rod topology. Science , this issue p. eabd6406

Funder

U.S. Department of Energy

NIH Office of the Director

Kavli Foundation

Swiss National Science Foundation

Studienstiftung des Deutschen Volkes

Deutsche Akademie der Naturforscher Leopoldina - Nationale Akademie der Wissenschaften

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference38 articles.