Comment on “Quantifying hot carrier and thermal contributions in plasmonic photocatalysis”-Reference-Cited by-同舟云学术

Comment on “Quantifying hot carrier and thermal contributions in plasmonic photocatalysis”

Published:2019-05-03 Issue:6439 Volume:364 Page:
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Sivan Yonatan¹²^ORCID,Baraban Joshua³^ORCID,Un Ieng Wai¹⁴^ORCID,Dubi Yonatan²³^ORCID

Affiliation:

1. Unit of Electro-Optics Engineering, Ben-Gurion University of the Negev, Beer-Sheva, Israel.

2. Ilse Katz Center for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Beer-Sheva, Israel.

3. Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, Israel.

4. Joan and Irwin Jacobs TIX Institute, National Tsing Hua University, Hsinchu City, Taiwan.

Abstract

Zhou et al . (Reports, 5 October 2018, p. 69) claim to have proven dominance of “hot” electrons over thermal effects in plasmonic photocatalysis. We identify experimental flaws that caused overestimation of the hot carrier contribution. As an alternative interpretation, we fully reproduce their data using a purely thermal Arrhenius law with a fixed activation energy and intensity-dependent heating.

Funder

Israel Science Foundation

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference14 articles.

1. Quantifying hot carrier and thermal contributions in plasmonic photocatalysis

2. Spectral emissivity of copper and nickel in the mid-infrared range between 250 and 900°C

3. Thermophysical properties of solid phase ruthenium measured by the pulse calorimetry technique over a wide temperature range

4. Design and testing of a high‐temperature emissometer for porous and particulate dielectrics

5. Absorption and reflection infrared spectra of MgO and other diatomic compounds

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