Tilt engineering of spontaneous polarization and magnetization above 300 K in a bulk layered perovskite

Author:

Pitcher Michael J.1,Mandal Pranab1,Dyer Matthew S.1,Alaria Jonathan2,Borisov Pavel1,Niu Hongjun1,Claridge John B.1,Rosseinsky Matthew J.1

Affiliation:

1. Department of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, UK.

2. Department of Physics, University of Liverpool, Liverpool L69 7ZE, UK.

Abstract

Tilting toward two properties Opposing electronic and symmetry constraints can make it difficult to combine some pairs of material properties in a single crystalline material. Magnetization and electrical polarization are such a pair, but their combination could be useful for applications such as magnetoelectric information storage. Pitcher et al. now show that careful design of chemical substitutions in a layered perovskite are both electrically polar and weakly ferromagnetic at temperatures up to 330 K. Science , this issue p. 420

Funder

European Research Council

Engineering and Physical Sciences Research Council (EPSRC)

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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