A hydrated crystalline calcium carbonate phase: Calcium carbonate hemihydrate

Author:

Zou Zhaoyong1ORCID,Habraken Wouter J. E. M.1ORCID,Matveeva Galina2ORCID,Jensen Anders C. S.1ORCID,Bertinetti Luca1,Hood Matthew A.1ORCID,Sun Chang-yu3,Gilbert Pupa U. P. A.34ORCID,Polishchuk Iryna5ORCID,Pokroy Boaz5ORCID,Mahamid Julia67ORCID,Politi Yael1ORCID,Weiner Steve8,Werner Peter9,Bette Sebastian10,Dinnebier Robert10ORCID,Kolb Ute211,Zolotoyabko Emil5,Fratzl Peter1ORCID

Affiliation:

1. Department of Biomaterials, Max Planck Institute of Colloids and Interfaces, Potsdam, Germany.

2. Johannes Gutenberg-Universität Mainz, Institut für Anorganische und Analytische Chemie, Mainz, Germany.

3. Department of Physics, University of Wisconsin–Madison, Madison, WI, USA.

4. Departments of Chemistry, Geoscience, and Materials Science, University of Wisconsin–Madison, Madison, WI, USA.

5. Department of Materials Science and Engineering, Technion-Israel Institute of Technology, Haifa, Israel.

6. Department of Molecular Structural Biology, Max Planck Institute of Biochemistry, Martinsried, Germany.

7. Structural and Computational Biology Unit, European Molecular Biology Laboratory, Heidelberg, Germany.

8. Department of Structural Biology, Weizmann Institute of Science, Rehovot, Israel.

9. Max Planck Institute of Microstructure Physics, Halle, Germany.

10. Max Planck Institute for Solid State Research, Stuttgart, Germany.

11. Institute of Applied Geosciences, TU Darmstadt, Darmstadt, Germany.

Abstract

Hydrous CaCO 3 gets a new structure Calcium carbonate (CaCO 3 ) forms important minerals on Earth and is a model system for understanding crystal nucleation. Three different structures of CaCO 3 are known, along with two structures that are hydrated. Zou et al. found a third hydrated CaCO 3 structure formed from amorphous CaCO 3 in the presence of magnesium ions. The discovery illustrates the importance of amorphous precursors for producing new materials. Science , this issue p. 396

Funder

Deutsche Forschungsgemeinschaft

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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