A liquid-liquid transition in supercooled aqueous solution related to the HDA-LDA transition-Reference-Cited by-同舟云学术

A liquid-liquid transition in supercooled aqueous solution related to the HDA-LDA transition

Published:2018-03-09 Issue:6380 Volume:359 Page:1127-1131
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Woutersen Sander¹^ORCID,Ensing Bernd¹²^ORCID,Hilbers Michiel¹^ORCID,Zhao Zuofeng³^ORCID,Angell C. Austen³^ORCID

Affiliation:

1. Van ’t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, Netherlands.

2. Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, 08193 Barcelona, Spain.

3. School of Molecular Sciences, Arizona State University, Tempe, AZ 85287, USA.

Abstract

Unmasking supercooled water transitions The unusual thermodynamic properties of water suggest that when supercooled, a second critical point should exist between two liquid phases that differ in density. Pure water crystallizes before such conditions can be reached. Woutersen et al. studied hydrazinium trifluoroacetate solutions that have similar hydrogen bonding to that of water. They observed a liquid-liquid transition near 190 K by using infrared spectroscopy and calorimetry. The liquid states were analogous to the predicted high- and low-density amorphous phases of water. Science , this issue p. 1127

Funder

National Science Foundation

John van Geuns Foundation

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference42 articles.

1. Phase behaviour of metastable water

2. Effect of Hydrogen Bonds on the Thermodynamic Behavior of Liquid Water

3. M. G. Sceats S. A. Rice in Water: A Comprehensive Treatise F. Franks Ed. (Plenum 1982) vol. 7 pp. 83–211.

4. Water: Anomalous compressibilities to 1.9 kbar and correlation with supercooling limits

5. Fluid-phase behavior of binary mixtures in which one component can have two critical points

Cited by 87 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Probing the Fermi resonance of pyridine surrounded by hydrogen bonding network by density functional theory;Journal of Molecular Structure;2024-06

2. Isocompositional liquid-liquid transition in dilute aqueous LiCl solutions;Physical Review Research;2024-05-01

3. Investigation of the Alcohols and Water Hydrogen Bonding Structure via Monomer Fraction Studies;Industrial & Engineering Chemistry Research;2024-03-26

4. Dynamics of Water Clusters Confined in Ionic Liquid at an Elevated Pressure;The Journal of Physical Chemistry Letters;2024-03-18

5. Attosecond-pump attosecond-probe x-ray spectroscopy of liquid water;Science;2024-03-08