Coupling of Nitrous Oxide and Methane by Global Atmospheric Chemistry

Author:

Prather Michael J.1,Hsu Juno1

Affiliation:

1. Department of Earth System Science, University of California, Irvine, CA 92697–3100, USA.

Abstract

Lingering Atmospheric Perturbations Nitrous oxide and methane are chemically active greenhouse gases whose atmospheric abundances are greatly influenced by anthropogenic emissions. Prather and Hsu (p. 952 ) used an atmospheric chemistry model to show how nitrous oxide emissions lower the concentration of tropospheric methane through a chain of chemical reactions that include stratospheric ozone depletion, changes in solar ultraviolet radiation fluxes, altered fluxes of ozone transport from the stratosphere to the troposphere, and increases in the amount of tropospheric hydroxyl radicals. This mechanism acts on a 108-year-long time scale—10 times longer than the atmospheric residence time of methane.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference21 articles.

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2. M. Prather et al . in Climate Change 2001: The Scientific Basis. Third Assessment Report of the Intergovernmental Panel on Climate Change J. T. Houghton et al . Eds. (Cambridge Univ. Press Cambridge 2001) pp. 239–287.

3. Nitrous Oxide: A Natural Source of Stratospheric NO

4. World Meteorological Organization (WMO) Atmospheric Ozone 1985: Assessment of Our Understanding of the Processes Controlling Its Present Distribution and Change R. T. Watson et al. Eds. (Global Ozone Research and Monitoring Project Report No. 16 WMO Geneva 1985).

5. Global long-lived chemical modes excited in a 3-D chemistry transport model: Stratospheric N2O, NOy, O3and CH4chemistry

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