Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water-Reference-Cited by-同舟云学术

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water

Published:2015-09-11 Issue:6253 Volume:349 Page:1208-1213
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Lin Song¹²,Diercks Christian S.¹³,Zhang Yue-Biao¹³⁴,Kornienko Nikolay¹,Nichols Eva M.¹²,Zhao Yingbo¹,Paris Aubrey R.¹,Kim Dohyung⁵,Yang Peidong¹³⁵⁶,Yaghi Omar M.¹³⁶⁷,Chang Christopher J.¹²⁸⁹

Affiliation:

1. Department of Chemistry, University of California, Berkeley, CA 94720, USA.

2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

3. Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

4. School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China.

5. Department of Materials Science and Engineering, University of California, Berkeley, CA 94720, USA.

6. Kavli Energy Nanoscience Institute, Berkeley, CA 94720, USA.

7. King Fahd University of Petroleum and Minerals, Dhahran 34464, Saudi Arabia.

8. Howard Hughes Medical Institute, University of California, Berkeley, CA 94720, USA.

9. Department of Molecular and Cell Biology, University of California, Berkeley, CA 94720, USA.

Abstract

Improving cobalt catalysts Tethering molecular catalysts together is a tried and trusted method for making them easier to purify and reuse. Lin et al. now show that the assembly of a covalent organic framework (COF) structure can also improve fundamental catalytic performance. They used cobalt porphyrin complexes as building blocks for a COF. The resulting material showed greatly enhanced activity for the aqueous electrochemical reduction of CO 2 to CO. Science , this issue p. 1208

Funder

U.S. Department of Energy

Lawrence Berkeley National Laboratory

DOE, Office of Science, Office of Basic Energy Sciences, Energy Frontier Research Center

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference68 articles.

1. Powering the planet: Chemical challenges in solar energy utilization

2. Powering the planet with solar fuel

3. Catalysis of the electrochemical reduction of carbon dioxide