Probing structural superlubricity of two-dimensional water transport with atomic resolution

Author:

Wu Da1ORCID,Zhao Zhengpu1ORCID,Lin Bo2ORCID,Song Yizhi1ORCID,Qi Jiajie3ORCID,Jiang Jian2ORCID,Yuan Zifeng1ORCID,Cheng Bowei1ORCID,Zhao Mengze3,Tian Ye1ORCID,Wang Zhichang1ORCID,Wu Muhong145ORCID,Bian Ke1ORCID,Liu Kai-Hui346ORCID,Xu Li-Mei146ORCID,Zeng Xiao Cheng27ORCID,Wang En-Ge1458ORCID,Jiang Ying1469ORCID

Affiliation:

1. International Center for Quantum Materials, School of Physics, Peking University, Beijing 100871, China.

2. Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong 999077, China.

3. State Key Laboratory for Mesoscopic Physics, Frontiers Science Center for Nano-optoelectronics, School of Physics, Peking University, Beijing 100871, China.

4. Interdisciplinary Institute of Light-Element Quantum Materials and Research Centre for Light-Element Advanced Materials, Peking University, Beijing 100871, China.

5. Songshan Lake Materials Laboratory, Institute of Physics, CAS and School of Physics, Liaoning University, Shenyang 110036, China.

6. Collaborative Innovation Center of Quantum Matter, Beijing 100871, China.

7. Hong Kong Institute for Clean Energy, City University of Hong Kong, Hong Kong 999077, China.

8. Tsientang Institute for Advanced Study, Zhejiang 310024, China.

9. New Cornerstone Science Laboratory, Peking University, Beijing 100871, China.

Abstract

Low-dimensional water transport can be drastically enhanced under atomic-scale confinement. However, its microscopic origin is still under debate. In this work, we directly imaged the atomic structure and transport of two-dimensional water islands on graphene and hexagonal boron nitride surfaces using qPlus-based atomic force microscopy. The lattice of the water island was incommensurate with the graphene surface but commensurate with the boron nitride surface owing to different surface electrostatics. The area-normalized static friction on the graphene diminished as the island area was increased by a power of ~–0.58, suggesting superlubricity behavior. By contrast, the friction on the boron nitride appeared insensitive to the area. Molecular dynamic simulations further showed that the friction coefficient of the water islands on the graphene could reduce to <0.01.

Publisher

American Association for the Advancement of Science (AAAS)

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