Eclogitic Diamond Formation at Jwaneng: No Room for a Recycled Component

Author:

Cartigny Pierre12,Harris Jeffrey W.12,Javoy Marc12

Affiliation:

1. P. Cartigny and M. Javoy, Laboratoire de Géochimie des Isotopes Stables, Université de Paris VII, Institut de Physique du Globe de Paris (IPGP), 4 Place Jussieu, 75251 Paris Cedex 05, France.

2. J. W. Harris, Department of Geology and Applied Geology, University of Glasgow, Glasgow G12 8QQ, Scotland, UK.

Abstract

Eclogitic diamonds have a large range of δ 13 C values, whereas peridotitic diamonds do not. Paired δ 15 N-δ 13 C-N variations in 40 eclogitic diamonds from the Jwaneng kimberlite in Botswana show that neither the influence of recycled biogenic carbon nor the global and primordial heterogeneity of mantle carbon are likely for the origin of the large δ 13 C range; the data instead support a fractionation process. It is proposed that carbonatitic mantle melts from which diamonds crystallize undergo different evolutions before diamond precipitation, when percolating through either a peridotite or an eclogite. These different evolutions, reflecting the presence or absence of olivine, can account for their respective δ 13 C distributions.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference38 articles.

1. J. J. Gurney in Kimberlites and Related Rocks J. Ross Ed. (Geol. Soc. Australia Spec. Pub. No. 14 1989) vol. 2 pp. 935-965

2. H. O. A. Meyer in Mantle Xenoliths P. H. Nixon Ed. (Wiley Chichester UK 1987) pp. 501-522.

3. J. W. Harris in The Properties of Natural and Synthetic Diamonds J. E. Field Ed. (Academic Press London 1992) pp. 345–394.

4. Sulfide inclusion chemistry and carbon isotopes of African diamonds

5. The carbon isotopic composition is given by δ13C= 13Cunk/12Cunk 13Cstd/12Cstd−1×1000 and the nitrogen isotopic composition is given by δ15N= 15Nunk/14Nunk 15Nstd/14Nstd−1×1000 where unk refers to the sample and std to the standard (Pee Dee Belemnite in the case of δ 13 C and atmosphere in the case of δ 15 N).

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