Galvanic Replacement Reactions in Metal Oxide Nanocrystals

Author:

Oh Myoung Hwan12,Yu Taekyung3,Yu Seung-Ho12,Lim Byungkwon4,Ko Kyung-Tae5,Willinger Marc-Georg6,Seo Dong-Hwa7,Kim Byung Hyo12,Cho Min Gee12,Park Jae-Hoon58,Kang Kisuk7,Sung Yung-Eun12,Pinna Nicola2910,Hyeon Taeghwan12

Affiliation:

1. Center for Nanoparticle Research, Institute for Basic Science (IBS), and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea.

2. World Class University (WCU) Program of Chemical Convergence for Energy and Environment and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea.

3. Department of Chemical Engineering, College of Engineering, Kyung Hee University, Yongin 446-701, Korea.

4. School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 440-746, Korea.

5. Cross-Coupled Complex Materials Research and Department of Physics, Pohang University of Science and Technology, Pohang 790-784, Korea.

6. Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society, Berlin 14195, Germany.

7. Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul 151-742, Korea.

8. Division of Advanced Materials Science, Pohang University of Science and Technology, Pohang 790-784, Korea.

9. Department of Chemistry and Centre for Research in Ceramics & Composite Materials, University of Aveiro, Aveiro 3810-193, Portugal.

10. Institut für Chemie, Humboldt-Universität zu Berlin, Berlin 12489, Germany.

Abstract

Hollowing Out Metal Oxide Nanoparticles Corrosion is normally a problem, but it can be useful, for example, when you wish to create hollow metal nanoparticles, whereby the reduction of one metal species in solution drives the dissolution of the core of the particle. Oh et al. (p. 964 ; see the Perspective by Ibáñez and Cabot ) adapted this approach to metal oxide nanoparticles by placing Mn 3 O 4 nanocrystals in solution with Fe 2+ ions, which replaces the nanocrystal exterior with γ-Fe 2 O 3 . At sufficiently high Fe 2+ concentrations, hollow γ-Fe 2 O 3 nanocages formed. These hollow structures could be used as anode materials for lithium ion batteries.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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