Palladium-catalyzed carbon-sulfur or carbon-phosphorus bond metathesis by reversible arylation

Author:

Lian Zhong1ORCID,Bhawal Benjamin N.1,Yu Peng1,Morandi Bill1ORCID

Affiliation:

1. Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr, Germany.

Abstract

Teaching sulfur and phosphorus to share Wouldn't it be nice if real chemistry worked like a modeling kit, and you could just pull a group off one molecule and tack it onto another? Lian et al. report that palladium catalysis can swap aryl rings between pairs of organosulfur or organophosphorus fragments in just this way. They showcase the sulfur swap by breaking down the commercial thermoplastic polyphenylene sulfide into simple monomers. Science , this issue p. 1059

Funder

Leverhulme Trust

Carlsbergfondet

China Sponsorship Council

Max-Planck-Gesellschaft

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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