Extinct 129 I in Halite from a Primitive Meteorite: Evidence for Evaporite Formation in the Early Solar System

Author:

Whitby James1,Burgess Ray1,Turner Grenville1,Gilmour Jamie1,Bridges John2

Affiliation:

1. Department of Earth Sciences, University of Manchester, Manchester M13 9PL, UK.

2. Department of Mineralogy, Natural History Museum, London, SW7 5BD, UK.

Abstract

Halite crystals from the Zag H3-6 chondrite contain essentially pure (monoisotopic) xenon-129 ( 129 Xe) produced in the early history of the solar system by the decay of short-lived iodine-129 ( 129 I) (half-life = 15.7 million years). Correlated release of 129 Xe and 128 Xe, produced artificially from 127 I by neutron irradiation, corresponds to an initial ( 129 I/ 127 I) ratio of (1.35 ± 0.05) × 10 −4 , close to the most primitive early solar system value. If the 129 Xe was produced by in situ decay, then the halite formed from an aqueous fluid within 2 million years of the oldest known solar system minerals.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference23 articles.

1. Asteroidal Water Within Fluid Inclusion-Bearing Halite in an H5 Chondrite, Monahans (1998)

2. J. N. Grossman Meteorit. Planet. Sci. 34 (suppl.) A182 (1999).

3. M. E. Zolensky R. J. Bodnar A. E. Rubin Meteorit. Planet. Sci. 34 (suppl.) A124 (1999).

4. This study used material separated from a 15 cm by 10 cm cut slice of Zag (Natural History Museum specimen 1999 M34). The meteorite slice shows a brecciated texture and consists of about 70% light-colored crystalline clasts of petrographic type 6 and 30% surrounding gray matrix of petrographic type 4 that contains recognizable chondrules. Lesser amounts of a third dark clast type that has not yet been sectioned are also present in the hand specimen. Ten halite grains (≤3 mm diameter) have been identified on the cut surfaces of the Zag specimen and four others have been found in thin sections; all fourteen are within the gray matrix. The grains are not present along obvious veins although some of their outlines (i.e. rhombohedral in the case of the largest one) indicate that they crystallized within opening fractures. Some of the halite grains also show signs of having undergone subsequent fracturing and recrystallization. Both the matrix and light clasts were found to be weakly shocked—S3 by the classification of (20). The halite grains have mottled colors varying from colorless to blue (predominant) and dark blue. Zolensky et al. (1) suggested that similar colors seen in Monahans (H5) halite grains—also present within a gray matrix—were a result of exposure to cosmic rays before the meteorite fall. No other minerals within Zag that might have a related paragenesis to the halite e.g. carbonates sulfates or clay veins have been found; the textures and major mineral assemblages seen in thin section are typical of equilibrated H group chondrite. There are no signs of any reaction between the halite and surrounding silicate phases. The halite was found to contain primary and secondary fluid inclusions and these are the subject of a separate study. Olivine and pyroxene mineral compositions (Hitachi 2500 SEM/EDS 15 kV 2 nA) are equilibrated Fo82 En83 in the light clasts and the matrix. However the meteorite has previously been classified as H3-6 (2) indicating the presence of unequilibrated material. Therefore Zag is heterogeneous on a coarse scale in respect to the range of petrographic types present within its components. The halite is nearly pure NaCl as K S and Ca were not detected (on the basis of multiple analyses within two separated grains and three grains in thin section; Cameca SX50 wds probe 15 kV 20 nA).

5. Gilmour J. D., Lyon I. C., Johnston W. A., Turner G., Rev. Sci. Instrum. 65, 617 (1994).

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