Black phosphorus composites with engineered interfaces for high-rate high-capacity lithium storage

Author:

Jin Hongchang1ORCID,Xin Sen23,Chuang Chenghao4ORCID,Li Wangda3ORCID,Wang Haiyun1ORCID,Zhu Jian5ORCID,Xie Huanyu1ORCID,Zhang Taiming1ORCID,Wan Yangyang1,Qi Zhikai1ORCID,Yan Wensheng6,Lu Ying-Rui7ORCID,Chan Ting-Shan7ORCID,Wu Xiaojun1ORCID,Goodenough John B.3ORCID,Ji Hengxing1ORCID,Duan Xiangfeng8ORCID

Affiliation:

1. Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China.

2. CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, China.

3. Department of Mechanical Engineering, The University of Texas at Austin, Austin, TX 78712, USA.

4. Department of Physics, Tamkang University, Tamsui 251, New Taipei City, Taiwan.

5. State Key Laboratory for Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.

6. National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China.

7. National Synchrotron Radiation Research Center, 300 Hsinchu, Taiwan.

8. Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095, USA.

Abstract

Engineering phosphorous anodes A focus of battery research has been the development of a range of lithium, sodium, and potassium cathodes, but improving anode materials is also an important goal. Silicon has shown some promise for replacing graphite because of its exceptional capacity, but the dramatic volume change during lithiation-delithiation processes often leads to failure. Jin et al. developed a composite that is made of black phosphorous and graphite in its core and covered with swollen polyaniline. In contrast to previous efforts, bonding between the carbon and phosphorous allows for a high charging rate without sacrifices in capacity and cycling stability. Science , this issue p. 192

Funder

Ministry of Science and Technology

National Natural Science Foundation of China

Minstry ov Science and Technoloy of China

Lawrence Berkeley National Laboratory BMR Program

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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