Synthesis and Characterization of a Stable Dibismuthene: Evidence for a Bi-Bi Double Bond-Reference-Cited by-同舟云学术

Synthesis and Characterization of a Stable Dibismuthene: Evidence for a Bi-Bi Double Bond

Published:1997-07-04 Issue:5322 Volume:277 Page:78-80
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Tokitoh Norihiro¹²,Arai Yoshimitsu¹²,Okazaki Renji¹²,Nagase Shigeru¹²

Affiliation:

1. N. Tokitoh, Y. Arai, R. Okazaki, Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113, Japan.

2. S. Nagase, Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, 1-1 Minami-osawa, Hachioji, Tokyo 192-03, Japan.

Abstract

Treatment of an overcrowded triselenatribismane, 2,4,6-tris(bis(trimethylsilyl)methyl)phenyl-1,3,5-triselena-2,4,6-tribismane, with hexamethylphosphorous triamide in toluene at 100°C resulted in the quantitative formation of a stable dibismuthene [TbtBi=BiTbt, where Tbt is 2,4,6-tris(bis(trimethylsilyl)methyl)phenyl], a compound containing a double bond formed between two bismuth atoms. The compound formed as deep purple crystals upon cooling. Ultraviolet-visible and Raman spectra, x-ray crystallographic structural analysis, and theoretical calculations provided evidence for the double bond character of the Bi–Bi bond.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference28 articles.

1. For reviews see F. G. A. Stone and R. West Eds. Adv. Organomet. Chem. 39 (1996)

2. G. Raabe and J. Michl in The Chemistry of Organic Silicon Compounds S. Patai and Z. Rappoport Eds. (Wiley New York 1989) part 2 chap. 17 pp. 1015-1142;

3. Barrau J., Escudié J., Satgé J., Chem. Rev. 90, 283 (1990);

4. Strained-Ring and Double-Bond Systems Consisting of the Group 14 Elements Si, Ge, and Sn

5. ; M. Yoshifuji in Multiple Bonds and Low Coordination in Phosphorus Chemistry M. Regitz and O. J. Scherer Eds. (Thieme Stuttgart Germany 1990) pp. 321–337.

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