Ultimate Permeation Across Atomically Thin Porous Graphene

Author:

Celebi Kemal1,Buchheim Jakob1,Wyss Roman M.1,Droudian Amirhossein1,Gasser Patrick1,Shorubalko Ivan2,Kye Jeong-Il3,Lee Changho3,Park Hyung Gyu1

Affiliation:

1. Nanoscience for Energy Technology and Sustainability, Department of Mechanical and Process Engineering, Eidgenössische Technische Hochschule (ETH) Zurich, Sonneggstrasse 3, CH-8092 Zürich, Switzerland.

2. Laboratory for Electronics/Metrology/Reliability, EMPA (Swiss Federal Laboratories for Materials Science and Technology), Überlandstrasse 129, CH-8600 Dübendorf, Switzerland.

3. Materials and Components R&D Laboratory, LG Electronics Advanced Research Institute, 38 Baumoe-ro, Seocho-gu, Seoul 137-724, Korea.

Abstract

Thin and Selective Outpourings When using a membrane to separate materials, the efficiency of the separation is limited by how fast the gas or liquid passes through the membrane and by how selective it is. Thinner membranes usually allow for faster flow rates but are usually less selective. Attempting to maintain selectivity, Celebi et al. (p. 289 ) developed a sophisticated way to drill holes of controlled diameter in a graphene sheet about two layers thick. For such a thin membrane, the primary barriers to separation come from entrance and exit from the holes and not from the motion through the membrane.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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