Micelle-directed chiral seeded growth on anisotropic gold nanocrystals

Author:

González-Rubio Guillermo1ORCID,Mosquera Jesús1ORCID,Kumar Vished1ORCID,Pedrazo-Tardajos Adrián2ORCID,Llombart Pablo34ORCID,Solís Diego M.5ORCID,Lobato Ivan2ORCID,Noya Eva G.4ORCID,Guerrero-Martínez Andrés3ORCID,Taboada José M.6ORCID,Obelleiro Fernando7ORCID,MacDowell Luis G.3ORCID,Bals Sara2ORCID,Liz-Marzán Luis M.189ORCID

Affiliation:

1. CIC biomaGUNE, Basque Research and Technology Alliance (BRTA), 20014 Donostia-San Sebastián, Spain.

2. Electron Microscopy for Materials Research (EMAT), University of Antwerp, 2020 Antwerp, Belgium.

3. Departamento de Química Física, Universidad Complutense de Madrid, 28040 Madrid, Spain.

4. Instituto de Química Física Rocasolano, CSIC, E-28006 Madrid, Spain.

5. Department of Electrical and Systems Engineering, University of Pennsylvania, Philadelphia, PA 19104, USA.

6. Departamento de Tecnología de los Computadores y de las Comunicaciones, University of Extremadura, 10003 Cáceres, Spain.

7. Departamento de Teoría de la Se ñal y Comunicaciones, University of Vigo, 36310 Vigo, Spain.

8. Ikerbasque, Basque Foundation for Science, 48013 Bilbao, Spain.

9. CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN), 20014 Donostia-San Sebastián, Spain.

Abstract

Groovy chiral gold particles Although plasmonic optical activity can arise from chiral assemblies of gold and silver nanoparticles, there are few examples of gold nanoparticles with intrinsic chirality and high optical activity. González-Rubio et al. show that morphological chirality can be induced during the seeded growth of gold nanoparticles, particularly for highly anisotropic nanorods. Chiral additives as cosurfactants formed helical micelles that directed the seeded growth to create grooves that maintained a chiral morphology. The resulting particles displayed high-intensity circular dichroism with anisotropy factors near 0.2 at near-infrared wavelengths. Science , this issue p. 1472

Funder

H2020 European Research Council

Ministerio de Ciencia, Innovación y Universidades

Red Espa ñola de Supercomputación

Red Espa ñola de Supercomputacion

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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