Single-Crystal Linear Polymers Through Visible Light–Triggered Topochemical Quantitative Polymerization-Reference-Cited by-同舟云学术

Single-Crystal Linear Polymers Through Visible Light–Triggered Topochemical Quantitative Polymerization

Published:2014-01-17 Issue:6168 Volume:343 Page:272-277
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Dou Letian¹²³,Zheng Yonghao¹⁴,Shen Xiaoqin¹,Wu Guang⁵,Fields Kirk⁶,Hsu Wan-Ching²³,Zhou Huanping²³,Yang Yang²³,Wudl Fred¹⁴⁵

Affiliation:

1. California NanoSystems Institute, University of California, Santa Barbara, CA 93106, USA.

2. Department of Materials Science and Engineering, University of California, Los Angeles, CA 90095, USA.

3. California NanoSystems Institute, University of California, Los Angeles, CA 90095, USA.

4. Advanced Institute for Materials Research at Tohoku University, a World Premier International Research Centers (WPI) Initiative Program (WPI-AIMR) and joint center with the California NanoSystems Institute, University of California, Santa Barbara, CA 93106, USA.

5. Department of Materials, University of California, Santa Barbara, CA 93106, USA.

6. Department of Mechanical Engineering, University of California, Santa Barbara, CA 93106, USA.

Abstract

Topochemical Polymerization In a topochemical reaction, chemical changes start at active sites in the solid and then proceed autocatalytically to neighboring regions. If one starts with a monomer that can form ordered structures similar to the final polymer, it is possible to polymerize chains in a fully ordered state and thus make very long single chains. Dou et al. (p. 272 ; see the Perspective by Goroff ) describe an unexpected visible-light–induced polymerization of derivatives of a dye. Two of the derivatives underwent photoinduced single-crystal-to-single-crystal topochemical polymerization.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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