Affiliation:
1. Department of Chemistry, McGill University, 801 Sherbrooke St. W., Montreal, QC H3A 0B8, Canada.
Abstract
Lighting the way coming and going
Catalysts accelerate chemical reactions by breaking existing bonds and then forming new ones. Often, the factors that favor the first process can muddle the second one, constraining a catalyst's generality. Torres
et al.
found that visible light excitation of a palladium complex can facilitate both the breaking and making of carbon-halogen bonds (see the Perspective by Kathe and Fleischer). The reaction specifically forms acid chlorides by carbonylation of a wide variety of alkyl or aryl bromides and iodides. These products in turn can react further to form amides and esters.
Science
, this issue p.
318
; see also p.
242
Funder
McGill University
Natural Sciences and Engineering Research Council of Canada
Fonds de Recherche du Québec Nature et Technologies
Mexican National Council of Science and Technology
Publisher
American Association for the Advancement of Science (AAAS)
Cited by
180 articles.
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