Design and control of gas diffusion process in a nanoporous soft crystal-Reference-Cited by-同舟云学术

Design and control of gas diffusion process in a nanoporous soft crystal

Published:2019-01-25 Issue:6425 Volume:363 Page:387-391
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Gu Cheng¹^ORCID,Hosono Nobuhiko¹^ORCID,Zheng Jia-Jia¹²^ORCID,Sato Yohei¹,Kusaka Shinpei¹^ORCID,Sakaki Shigeyoshi²^ORCID,Kitagawa Susumu¹^ORCID

Affiliation:

1. Institute for Integrated Cell-Material Sciences, Kyoto University Institute for Advanced Study, Kyoto University, Yoshida Ushinomiya-cho, Sakyo-ku, Kyoto 606-8501, Japan.

2. Fukui Institute for Fundamental Chemistry, Kyoto University, Takano Nishihiraki-cho 34-4, Sakyo-ku, Kyoto 606-8103, Japan.

Abstract

Flexibility in gas absorption Soft materials such as porous coordination polymer (PCP) can exhibit temperature-dependent flexible motions of their internal pores that can assist in gas separation and storage. Gu et al. designed a copper-based PCP with a ligand that contains phenothiazine-5,5-dioxide. The entrances to the porous cages changed size with temperature, when these functional groups underwent flipping motions. The change in gate size could lead to high selectivity for gas absorption and enabled the separation of oxygen from argon and of ethylene from ethane as well as long-term gas storage under ambient conditions. Science , this issue p. 387

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science, and Technology

Japan Science and Technology Agency

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference59 articles.

1. Oak Ridge National Laboratory Materials for Separation Technologies: Energy and Emission Reduction Opportunities (Oak Ridge National Laboratory 2005).

2. S. M. Auerbach K. A. Carrado P. K. Dutta Handbook of Zeolite Science and Technology (Marcel Dekker 2003).

3. D. W. Beck Zeolite Molecular Sieves (John Wiley & Sons 1974).

4. R. C. Bansal M. Goyal Activated Carbon Adsorption (Taylor & Francis Group CRC Press 2005).

5. R. Xu W. Pang J. Yu Q. Huo J. Chen Chemistry of Zeolites and Related Porous Materials: Synthesis and Structure (John Wiley and Sons 2007).

Cited by 327 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Temperature‐Dependent Separation of CO₂ from Light Hydrocarbons in a Porous Self‐Assembly of Vertexes Sharing Octahedra;Advanced Science;2024-02-02

2. A highly stable yttrium-based metal-organic framework with two-fold interpenetrated and cage-like pore structure for one-step purification of ethylene from ethylene/ethane mixture;Separation and Purification Technology;2024-02

3. Functionalized metal–organic and hydrogen-bonded organic frameworks for C2H4/C2H6 separation;Separation and Purification Technology;2024-02

4. Hydrogen bond unlocking-driven pore structure control for shifting multi-component gas separation function;Nature Communications;2024-01-27

5. Atomic observation and structural evolution of covalent organic framework rotamers;Proceedings of the National Academy of Sciences;2024-01-22