Ice Core Records of Atmospheric N 2 O Covering the Last 106,000 Years

Author:

Sowers Todd1,Alley Richard B.1,Jubenville Jennifer1

Affiliation:

1. Department of Geosciences and the EMS Environment Institute, Pennsylvania State University, UniversityPark, PA 16802, USA.

Abstract

Paleoatmospheric records of trace-gas concentrations recovered from ice cores provide important sources of information on many biogeochemical cycles involving carbon, nitrogen, and oxygen. Here, we present a 106,000-year record of atmospheric nitrous oxide (N 2 O) along with corresponding isotopic records spanning the last 30,000 years, which together suggest minimal changes in the ratio of marine to terrestrial N 2 O production. During the last glacial termination, both marine and oceanic N 2 O emissions increased by 40 ± 8%. We speculate that our records do not support those hypotheses that invoke enhanced export production to explain low carbon dioxide values during glacial periods.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference47 articles.

1. Current N 2 O emissions from the terrestrial biosphere are estimated to be 12 ± 3 Tg N/year and preanthropogenic estimates are ∼7 Tg N/year ( 12 36-39 ). Marine N 2 O emissions are estimated to be 4 ± 2 Tg N/year ( 40 41 ). About 98% of the total atmospheric N 2 O sink occurs in the stratosphere. Minschwaner et al. ( 42 ) estimated the 1980 value to be 12 ± 4 Tg N/year corresponding to a mean atmospheric lifetime of 118 ± 25 years ( 43 ).

2. J. R. Holton et al., Rev. Geophys.33, 403 (1995).

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4. J. Fluckiger et al., Global Biogeochem. Cycles16, 1010, doi:10.1029/2001GB001417 (2002).

5. M. Leuenberger, U. Siegenthaler, Nature360, 449 (1992).

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