Ordered macro-microporous metal-organic framework single crystals-Reference-Cited by-同舟云学术

Ordered macro-microporous metal-organic framework single crystals

Published:2018-01-12 Issue:6372 Volume:359 Page:206-210
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Shen Kui¹^ORCID,Zhang Lei¹,Chen Xiaodong¹,Liu Lingmei²,Zhang Daliang³^ORCID,Han Yu²^ORCID,Chen Junying¹^ORCID,Long Jilan¹,Luque Rafael⁴^ORCID,Li Yingwei¹^ORCID,Chen Banglin⁵^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.

2. Advanced Membranes and Porous Materials Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia.

3. Imaging and Characterization Core Lab, KAUST, Thuwal 23955-6900, Saudi Arabia.

4. Departamento de Química Orgánica, Universidad de Córdoba, Edificio Marie Curie, Carretera Nacional IV-A, Km 396, E14014, Córdoba, Spain.

5. Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249, USA.

Abstract

Mesoporous metal-organic frameworks The diffusion limitations on gas storage and catalytic reaction of microporous materials can often be overcome if they are incorporated into a mesoporous structure with much larger pores. Shen et al. grew ordered arrays of microcrystals of the ZIF-8 metal-organic framework, in which zinc ions are bridged by 2-methylimidazole linkers, inside a porous polystyrene template. These materials showed higher reaction rates for the Knoevenagel reaction between benzaldehydes and malononitriles and better catalyst recyclability. Science , this issue p. 206

Funder

Welch Foundation

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference31 articles.

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