Affiliation:
1. Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana, IL 61801, USA.
Abstract
Where Pd and B meet in Suzuki coupling
The Suzuki-Miyaura reaction is widely used to form carbon-carbon bonds. It operates by transferring a carbon center from boron to palladium, although the handoff itself happens too quickly to see. Thomas and Denmark have caught sight of the previously elusive intermediate complexes linking palladium to boron through an intervening oxygen. Using low-temperature nuclear magnetic resonance spectroscopy, they characterized the intermediate structures just before the carbon transfer event.
Science
, this issue p.
329
Publisher
American Association for the Advancement of Science (AAAS)
Cited by
266 articles.
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