A liquid metal reaction environment for the room-temperature synthesis of atomically thin metal oxides

Author:

Zavabeti Ali1ORCID,Ou Jian Zhen1ORCID,Carey Benjamin J.1ORCID,Syed Nitu1ORCID,Orrell-Trigg Rebecca1ORCID,Mayes Edwin L. H.2,Xu Chenglong1ORCID,Kavehei Omid1ORCID,O’Mullane Anthony P.3ORCID,Kaner Richard B.4ORCID,Kalantar-zadeh Kourosh1ORCID,Daeneke Torben1ORCID

Affiliation:

1. School of Engineering, RMIT University, Melbourne, Victoria 3001, Australia.

2. School of Applied Sciences, RMIT University, Melbourne, Victoria 3001, Australia.

3. School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, Brisbane, Queensland 4001, Australia.

4. Department of Chemistry and Biochemistry, Department of Materials Science and Engineering, and California NanoSystems Institute, University of California, Los Angeles, CA 90095, USA.

Abstract

Expanding the world of 2D materials Two-dimensional (2D) materials have a wide variety of potential applications in the electronics industry. However, certain compositions of 2D materials are difficult to obtain owing to the challenges in exfoliating thin sheets from bulk crystals. Zavabeti et al. exploited liquid metals to synthesize 2D Ga 2 O 3 , HfO 2 , Gd 2 O 3 , and Al 2 O 3 . The 2D sheets appear as a surface layer in gallium-based liquid metals after the Hf, Gd, or Al is dissolved into the bulk alloy. The 2D oxide that appears on the surface is the oxide with the lowest energy, suggesting that it should be possible to make other 2D oxides by using the same process. Science , this issue p. 332

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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