Enhanced Sulfur and Coking Tolerance of a Mixed Ion Conductor for SOFCs: BaZr 0.1 Ce 0.7 Y 0.2– x Yb x O 3–δ

Abstract

Cleaning Solid Oxide Fuel Cells Solid oxide fuel cells, which operate between 500° and 1000°C, transport oxygen through a ceramic material. At these temperatures, metals that catalyze hydrocarbon reforming reactions can also be incorporated so that conventional fuels such as methane can power the cell. One problem, however, has been rapid deactivation by sulfur impurities and carbon buildup. Yang et al. (p. 126 ; see the Perspective by Selman ) report that doping of a barium zirconate-cerate with the rare-earths Y and Yb creates a material that transports both protons and oxygen ions at 750°C. This material, when used with nickel at the fuel cell anode, resists deactivation even when traces of hydrogen sulfide are present, apparently through enhanced ability to supply or remove water during surface reactions.