Affiliation:
1. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
Abstract
Size-dependent development of the hydrogen bond network structure in largesized clusters of protonated water, H
+
(H
2
O)
n
(
n
= 4 to 27), was probed by infrared spectroscopy of OH stretches. Spectral changes with cluster size demonstrate that the chain structures at small sizes (
n
≲ 10) develop into two-dimensional net structures (∼10 <
n
< 21), and then into nanometer-scaled cages (
n
≥ 21).
Publisher
American Association for the Advancement of Science (AAAS)
Cited by
508 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献