Weaving of organic threads into a crystalline covalent organic framework-Reference-Cited by-同舟云学术

Weaving of organic threads into a crystalline covalent organic framework

Published:2016-01-22 Issue:6271 Volume:351 Page:365-369
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Liu Yuzhong¹,Ma Yanhang²,Zhao Yingbo¹,Sun Xixi¹,Gándara Felipe³,Furukawa Hiroyasu¹,Liu Zheng⁴,Zhu Hanyu⁵,Zhu Chenhui⁶,Suenaga Kazutomo⁴,Oleynikov Peter²,Alshammari Ahmad S.⁷,Zhang Xiang⁵⁸,Terasaki Osamu²⁹,Yaghi Omar M.¹⁷

Affiliation:

1. Department of Chemistry, University of California, Berkeley, Materials Sciences Division, Lawrence Berkeley National Laboratory, and Kavli Energy NanoSciences Institute, Berkeley, CA 94720, USA.

2. Department of Materials and Environmental Chemistry, Stockholm University, SE-10691 Stockholm, Sweden.

3. Department of New Architectures in Materials Chemistry, Materials Science Institute of Madrid, Consejo Superior de Investigaciones Científicas, Madrid 28049, Spain.

4. Nanomaterials Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba 305-8565, Japan.

5. NSF Nanoscale Science and Engineering Center (NSEC), University of California at Berkeley, 3112 Etcheverry Hall, Berkeley, CA 94720, USA.

6. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

7. King Abdulaziz City of Science and Technology, Post Office Box 6086, Riyadh 11442, Saudi Arabia.

8. Material Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA.

9. School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China.

Abstract

Weaving organic threads Woven fabrics are inherently flexible. Liu et al. created a molecular fabric analog using metal-organic frameworks (see the Perspective by Gutierrez-Puebla). Phenanthroline ligands on a copper metal complex directed the addition of organic linkers via imine bonds to create helical organic threads with woven texture. Removing the copper allowed the strands to slide against each other and increased the elasticity of the material 10-fold. Science , this issue p. 365 ; see also p. 336

Funder

BASF SE

U.S. Department of Defense, Defense Threat Reduction Agency

Spanish Ministry of Economy and Competitiveness

Grant-in-Aid for Scientific Research

U.S. Department of Energy

National Science Foundation (NSF)

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference23 articles.