Defibrillation of soft porous metal-organic frameworks with electric fields-Reference-Cited by-同舟云学术

Defibrillation of soft porous metal-organic frameworks with electric fields

Published:2017-10-20 Issue:6361 Volume:358 Page:347-351
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Knebel A.¹^ORCID,Geppert B.¹,Volgmann K.¹^ORCID,Kolokolov D. I.²³^ORCID,Stepanov A. G.²³^ORCID,Twiefel J.⁴^ORCID,Heitjans P.¹,Volkmer D.⁵^ORCID,Caro J.¹^ORCID

Affiliation:

1. Institute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, 30167 Hannover, Germany.

2. Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Novosibirsk 630090, Russia.

3. Novosibirsk State University, Novosibirsk 630090, Russia.

4. Institute for Dynamic and Vibration Research, Leibniz University Hannover, 30167 Hannover, Germany.

5. Institute of Physics, Chair of Solid State and Materials Chemistry, Augsburg University, 86135 Augsburg, Germany.

Abstract

Tuning porosity with electric fields Many metal-organic framework (MOF) compounds exhibit soft porosity—i.e., their lattices can undergo considerable deformation. Knebel et al. formed membrane layers of the MOF ZIF-8 and found that it was converted into a polar polymorph with a stiffer lattice in response to an applied electric field (see the Perspective by Gascon). This change reduced gas transport but, for certain gas mixtures such as propane and propene, also improved their separation factor. Science , this issue p. 347 ; see also p. 303

Funder

Deutsche Forschungsgemeinschaft

Russian Academy of Sciences

Russian Science Foundation

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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