Rational synthesis of organic thin films with exceptional long-range structural integrity

Abstract

Standing at order Thin films of organic molecules on solid substrates tend to nucleate at many sites and grow multiple domains. However, one large uniform film would be much more desirable in device applications. Seiki et al. designed organic molecules that filled space in a hexagonal tiling; a propeller-like triptycene base adhered to crystalline surfaces and alkyl tails extended away from it. The authors could make well-ordered multilayer films up to centimeter length scales. Science , this issue p. 1122