Optical Spectroscopy of Individual Single-Walled Carbon Nanotubes of Defined Chiral Structure-Reference-Cited by-同舟云学术

Optical Spectroscopy of Individual Single-Walled Carbon Nanotubes of Defined Chiral Structure

Published:2006-04-28 Issue:5773 Volume:312 Page:554-556
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Sfeir Matthew Y.¹²³⁴⁵,Beetz Tobias¹²³⁴⁵,Wang Feng¹²³⁴⁵,Huang Limin¹²³⁴⁵,Huang X. M. Henry¹²³⁴⁵,Huang Mingyuan¹²³⁴⁵,Hone J.¹²³⁴⁵,O'Brien Stephen¹²³⁴⁵,Misewich J. A.¹²³⁴⁵,Heinz Tony F.¹²³⁴⁵,Wu Lijun¹²³⁴⁵,Zhu Yimei¹²³⁴⁵,Brus Louis E.¹²³⁴⁵

Affiliation:

1. Department of Chemistry, Columbia University, 3000 Broadway, New York, NY 10027, USA.

2. Department of Physics and Electrical Engineering, Columbia University, 3000 Broadway, New York, NY 10027, USA.

3. Department of Applied Physics and Applied Mathematics, Columbia University, 3000 Broadway, New York, NY 10027, USA.

4. Department of Mechanical Engineering, Columbia University, 3000 Broadway, New York, NY 10027, USA.

5. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY 11973, USA.

Abstract

We simultaneously determined the physical structure and optical transition energies of individual single-walled carbon nanotubes by combining electron diffraction with Rayleigh scattering spectroscopy. These results test fundamental features of the excited electronic states of carbon nanotubes. We directly verified the systematic changes in transition energies of semiconducting nanotubes as a function of their chirality and observed predicted energy splittings of optical transitions in metallic nanotubes.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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