Comment on “Reversible disorder-order transitions in atomic crystal nucleation”

Author:

Yu Cheng-Long1ORCID,Cheng Hang1,Qi Yong2ORCID,Song Jie1,Yang Chen-Guang1,Wen Yu1,Wang Xiu-Feng1

Affiliation:

1. School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi’an 710021, China.

2. School of Electronic Information and Artificial Intelligence, Shaanxi University of Science and Technology, Xi’an 710021, China.

Abstract

Jeon et al . (Reports, 29 January 2021, p. 498) reported reversible fluctuations between disordered and crystalline states during nucleation. We argue that the adoption of “magic numbers” for separation of the size range into three parts is misleading when using the sigmoid functions and that their figure 3B was wrongly illustrated. The crystal shape effect was neglected during theoretical analysis.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference12 articles.

1. Reversible disorder-order transitions in atomic crystal nucleation

2. B. G. M. Vandeginste D. L. Massart L. M. C. Buydens S. De Jong P. J. Lewi J. Smeyers-Verbeke Chapter 44: Artificial neural networks. Data Handling Sci. Tech. 20 649–699 (1998). doi: 10.1016/S0922-3487(98)80054-3

3. Observation of Transient Structural-Transformation Dynamics in a Cu 2 S Nanorod

4. Finite-size effects at temperature-driven first-order transitions

5. When s approaches s 0 the energy barrier between the two states can be very small; then reversible fluctuation with crystal size can reasonably take place which can be confirmed by the wide scattering of TFCSs in Fig. 1A in the range 1.26 to 1.78 nm 2 . But this is not in the very early stage of nucleation as claimed by the authors in their figure 3B (top) but rather around the critical size.

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