Vibrational relaxation and microsolvation of DF after F-atom reactions in polar solvents-Reference-Cited by-同舟云学术

Vibrational relaxation and microsolvation of DF after F-atom reactions in polar solvents

Published:2015-01-30 Issue:6221 Volume:347 Page:530-533
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Dunning G. T.¹,Glowacki D. R.¹²³⁴,Preston T. J.¹,Greaves S. J.⁵,Greetham G. M.⁶,Clark I. P.⁶,Towrie M.⁶,Harvey J. N.¹,Orr-Ewing A. J.¹

Affiliation:

1. School of Chemistry, University of Bristol, Cantock’s Close, Bristol BS8 1TS, UK.

2. Department of Computer Science, Merchant Venturers Building, Woodland Road, Bristol BS8 1UB, UK.

3. Photon Ultrafast Laser Science and Engineering (PULSE) Institute and Department of Chemistry, Stanford University, Stanford, CA 94305, USA.

4. SLAC National Accelerator Laboratory, Menlo Park, CA 94025, USA.

5. School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, UK.

6. Central Laser Facility, Research Complex at Harwell, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Oxford, Didcot, Oxfordshire OX11 0QX, UK.

Abstract

Deuterium fluoride gets born shivering Modern spectroscopic techniques can analyze collisions between gas phase molecules in exquisite detail, highlighting exactly which vibrations and rotations come into play. However, much chemistry of interest takes place in solution, where it's harder to tease out what happens. Dunning et al. applied infrared spectroscopy to study solution-phase formation of deuterium fluoride (DF) from F atoms, a longstanding test bed of gas phase dynamics. The DF product vibrated for a surprisingly long time before dissipating its energy to the surrounding solvent molecules. Science , this issue p. 530

Funder

European Research Council

Engineering and Physical Sciences Research Council

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference50 articles.

1. R. D. Levine Molecular Reaction Dynamics (Cambridge Univ. Press Cambridge 2005).

2. Molecular beam studies of the F+H2 reaction

3. Transition-State Spectroscopy of Partial Wave Resonances in the F + HD Reaction

4. The Transition State of the F + H 2 Reaction

5. The rate of the F + H2 reaction at very low temperatures

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