Methylhydroxycarbene: Tunneling Control of a Chemical Reaction-Reference-Cited by-同舟云学术

Methylhydroxycarbene: Tunneling Control of a Chemical Reaction

Published:2011-06-10 Issue:6035 Volume:332 Page:1300-1303
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Schreiner Peter R.¹,Reisenauer Hans Peter¹,Ley David¹,Gerbig Dennis¹,Wu Chia-Hua²,Allen Wesley D.²

Affiliation:

1. Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen, Germany.

2. Department of Chemistry and Center for Computational Chemistry, University of Georgia, Athens, GA 30602–2525, USA.

Abstract

Quantum tunneling induces the opposite outcome expected from traditional kinetic factors in a chemical rearrangement.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference78 articles.

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5. Rearrangement and substitution, in anionotropic systems. Part III. Mechanism of, and equilibrium in, anionotropic change;Catchpole A. G.;J. Chem. Soc.,1944

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