Mechanisms of Ordering in Striped Patterns

Author:

Harrison Christopher1,Adamson Douglas H.2,Cheng Zhengdong1,Sebastian John M.3,Sethuraman Srinivasan4,Huse David A.1,Register Richard A.3,Chaikin P. M.1

Affiliation:

1. Department of Physics,

2. Princeton Materials Institute,

3. Department of Chemical Engineering, Princeton University, Princeton, NJ 08544, USA.

4. Jet Propulsion Laboratory, 4800 Oak Grove Drive, Mailstop 302-306, Pasadena, CA 91109, USA.

Abstract

We have studied the ordering dynamics of the striped patterns of a single layer of cylindrical block copolymer microdomains in a thin film. By tracking disclinations during annealing with time-lapse atomic force microscopy, we observe a dominant mechanism of disclination annihilation involving three or four disclinations (quadrupoles). Pairwise disclination annihilation events are suppressed as a result of the topological constraints in this system. The kinetic scaling laws with exponents observed here are consistent with topologically allowed annihilation events involving multiple disclinations. The results provide insight into two-dimensional pattern formation and may lead to the successful application of block copolymer lithography.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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