Multi-Atom Resonant Photoemission: A Method for Determining Near-Neighbor Atomic Identities and Bonding-Reference-Cited by-同舟云学术

Multi-Atom Resonant Photoemission: A Method for Determining Near-Neighbor Atomic Identities and Bonding

Published:1998-07-31 Issue:5377 Volume:281 Page:679-683
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Kay A.¹,Arenholz E.¹,Mun S.¹,Garcı́a de Abajo F. J.¹,Fadley C. S.¹,Denecke R.¹,Hussain Z.¹,Van Hove M. A.¹

Affiliation:

1. A. Kay, S. Mun, C. S. Fadley, R. Denecke, Department of Physics, University of California at Davis, Davis, CA 95616, USA, and Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA. E. Arenholz, F. J. Garcı́a de Abajo, M. A. Van Hove, Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA. Z. Hussain, Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

Abstract

Measurements and theoretical calculations are reported for an interatomic multi-atom resonant photoemission (MARPE) effect that permits direct determination of near-neighbor atomic identities (atomic numbers). MARPE occurs when the photon energy is tuned to a core-level absorption edge of an atom neighboring the emitting atom, with the emitting level having a lower binding energy than the resonant level. Large peak-intensity enhancements of 33 to 105 percent and energy-integrated effects of 11 to 29 percent were seen in three metal oxides. MARPE should also be sensitive to bond distance, bonding type, and magnetic order, and be observable via the secondary processes of x-ray fluorescence and Auger decay.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference28 articles.

1. The UWXAFS analysis package: philosophy and details

2. ; M. Newville et al. ibid. p. 154; and references therein.

3. M. A. Van Hove W. H. Weinberg C.-M. Chan Low Energy Electron Diffraction (Springer-Verlag Heidelberg Germany 1986).

4. DIFFRACTION AND HOLOGRAPHY WITH PHOTOELECTRONS AND FLUORESCENT X-RAYS

5. and references therein.

Cited by 110 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Interplay between disorder and electronic correlations in compositionally complex alloys;Nature Communications;2024-09-12

2. Electronic and Crystal Structure of New Cr_xZrSe₂ Intercalation Compounds;Inorganic Chemistry;2024-01-04

3. Charge transfer in Nb1-xVxSe2 materials: Synchrotron radiation spectroscopy study;Journal of Physics and Chemistry of Solids;2023-08

4. Search for the interatomic Auger effect in Nitrous Oxide;Journal of Electron Spectroscopy and Related Phenomena;2023-05

5. An unusual Cu/Te hybridization in the Cu0.3ZrTe2 intercalation compound;Journal of Alloys and Compounds;2022-11