Dense dislocation arrays embedded in grain boundaries for high-performance bulk thermoelectrics

Author:

Kim Sang Il1,Lee Kyu Hyoung2,Mun Hyeon A34,Kim Hyun Sik15,Hwang Sung Woo1,Roh Jong Wook1,Yang Dae Jin1,Shin Weon Ho1,Li Xiang Shu1,Lee Young Hee34,Snyder G. Jeffrey35,Kim Sung Wng34

Affiliation:

1. Materials Research Center, Samsung Advanced Institute of Technology, Samsung Electronics, Suwon 443-803, South Korea.

2. Department of Nano Applied Engineering, Kangwon National University, Chuncheon 200-701, South Korea.

3. Department of Energy Science, Sungkyunkwan University, 300 Cheoncheon-dong, Jangan-gu, Suwon 440-746, South Korea.

4. IBS Center for Integrated Nanostructure Physics, Institute for Basic Science, Sungkyunkwan University, Suwon 440-746, South Korea.

5. Materials Science, California Institute of Technology, Pasadena, California 91125, USA.

Abstract

Squeezing out efficient thermoelectrics Thermoelectric materials hold the promise of converting waste heat into electricity. The challenge is to develop high-efficiency materials that are not too expensive. Kim et al. suggest a pathway for developing inexpensive thermoelectrics. They show a dramatic improvement of efficiency in bismuth telluride samples by quickly squeezing out excess liquid during compaction. This method introduces grain boundary dislocations in a way that avoids degrading electrical conductivity, which makes a better thermoelectric material. With the potential for scale-up and application to cheaper materials, this discovery presents an attractive path forward for thermoelectrics. Science , this issue p. 109

Funder

National Research Foundation of Korea

Human Resources Development

Korea government Ministry of Trade, Industry, and Energy

AFOSR MURI

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference55 articles.

1. Cooling, Heating, Generating Power, and Recovering Waste Heat with Thermoelectric Systems

2. H. Scherrer S. Scherrer in Thermoelectrics Handbook Macro to Nano D. M. Rowe Ed. (CRC Boca Raton FL 2006) chap. 27.

3. R. J. Buist A simplified method for thermoelectric heat pump optimization. in 3rd International Conference on Thermoelectric Energy Conversion Arlington Texas 12 to 14 May 1980 (IEEE New York 1980) pp. 130–134.

4. H. J. Goldsmid in Electronic Refrigeration (Pion London 1986) chaps. 2 and 7.

5. New Directions for Low-Dimensional Thermoelectric Materials

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