Field Measurement of Slow Metamorphic Reaction Rates at Temperatures of 500° to 600°C

Author:

Baxter Ethan F.1,DePaolo Donald J.1

Affiliation:

1. Department of Geology and Geophysics, University of California, 301 McCone Hall, Berkeley, CA 94720, USA.

Abstract

High-temperature metamorphic reaction rates were measured using strontium isotopic ratios of garnet and whole rock from a field site near Simplon Pass, Switzerland. For metamorphic conditions of cooling from 612° ± 17°C to 505° ± 15°C at pressures up to 9.1 kilobars, the inferred bulk fluid-rock exchange rate is 1.3 −0.4 +1.1 × 10 −7 grams of solid reacted per gram of solid per year, several orders of magnitude lower than laboratory-based estimates. The inferred reaction rate suggests that mineral chemistry may lag the evolving conditions in Earth's crust during mountain building.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference41 articles.

1. See for example

2. Fluid Flow and Diffusion in the Waterville Limestone, South--Central Maine: Constraints from Strontium, Oxygen and Carbon Isotope Profiles

3. Nicolaysen L. O., Ann. N.Y. Acad. Sci. 2, 198 (1961);

4. ; F. S. Spear Metamorphic Phase Equilibria and Pressure-Temperature-Time Paths (Mineralogical Society of America Washington DC 1993).

5. J. V. Walther and B. J. Wood in Fluid-Rock Interactions During Metamorphism J. V. Walther and B. J. Wood Eds. (Springer-Verlag New York 1986) pp. 195–211.

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