Imperfect Oriented Attachment: Dislocation Generation in Defect-Free Nanocrystals

Author:

Penn R. Lee1,Banfield Jillian F.1

Affiliation:

1. R. L. Penn, Materials Science Program, University of Wisconsin–Madison, Madison, WI 53706, USA. J. F. Banfield, Mineralogical Institute, Graduate School of Science, University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113, Japan.

Abstract

Dislocations are common defects in solids, yet all crystals begin as dislocation-free nuclei. The mechanisms by which dislocations form during early growth are poorly understood. When nanocrystalline materials grow by oriented attachment at crystallographically specific surfaces and there is a small misorientation at the interface, dislocations result. Spiral growth at two or more closely spaced screw dislocations provides a mechanism for generating complex polytypic and polymorphic structures. These results are of fundamental importance to understanding crystal growth.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference32 articles.

1. The two most commonly noted mechanisms of crystal growth are spiral growth around a dislocation and surface nucleation followed by two-dimensional growth. Both mechanisms involve the addition of atoms to reactive surface sites from solution vapor or melt.

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5. ; J. Friedel Dislocations (Pergamon New York 1964). M. F. Hochella Mineral-Water Interface Geochemistry vol. 23 of Reviews in Mineralogy M. F. Hochella and A. F. White Eds. (Mineralogical Society of America Washington DC 1990) pp. 87–132.

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