Efficient tandem solar cells with solution-processed perovskite on textured crystalline silicon

Author:

Hou Yi1ORCID,Aydin Erkan2ORCID,De Bastiani Michele2ORCID,Xiao Chuanxiao3,Isikgor Furkan H.2ORCID,Xue Ding-Jiang1ORCID,Chen Bin1,Chen Hao1,Bahrami Behzad4ORCID,Chowdhury Ashraful H.4ORCID,Johnston Andrew1ORCID,Baek Se-Woong1ORCID,Huang Ziru1ORCID,Wei Mingyang1,Dong Yitong1ORCID,Troughton Joel2,Jalmood Rawan2,Mirabelli Alessandro J.2ORCID,Allen Thomas G.2ORCID,Van Kerschaver Emmanuel2,Saidaminov Makhsud I.1ORCID,Baran Derya2ORCID,Qiao Qiquan4ORCID,Zhu Kai3ORCID,De Wolf Stefaan2ORCID,Sargent Edward H.1ORCID

Affiliation:

1. Department of Electrical and Computer Engineering, University of Toronto, Toronto, Ontario M5S 1A4, Canada.

2. KAUST Solar Center (KSC), Physical Sciences and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia.

3. National Renewable Energy Laboratory (NREL), Golden, CO 80401, USA.

4. Department of Electrical Engineering, Center for Advanced Photovoltaics, South Dakota State University, Brookings, SD 57007, USA.

Abstract

Growing perovskite on textured silicon Wide–band gap perovskites could boost the efficiency of silicon solar cells by forming tandem cells, but usually the perovskite must be grown on a smoothed side of the silicon cell because the material grown on the rough light-trapping side often does not fully coat the silicon surface and its rough texture is prone to phase separation. Hou et al. grew thick films of a perovskite with a band gap of ∼1.68 electron volts and used a passivant, 1-butanethiol, to limit its phase separation. The tandem cells had a certified power conversion efficiency of 25.7% and had negligible losses after 400 hours of operation. Science , this issue p. 1135

Funder

King Abdullah University of Science and Technology

U.S. Department of Energy

EDA University Center Program

US Department of the Navy, Office of Naval Research

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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