Relaxation Mechanism of the Hydrated Electron-Reference-Cited by-同舟云学术

Relaxation Mechanism of the Hydrated Electron

Published:2013-12-20 Issue:6165 Volume:342 Page:1496-1499
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Elkins Madeline H.¹,Williams Holly L.¹,Shreve Alexander T.²,Neumark Daniel M.¹³

Affiliation:

1. Department of Chemistry, University of California, Berkeley, CA 94720, USA.

2. Intel Corporation, Hillsboro, OR 97124, USA.

3. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

Abstract

Relaxing in a Water Jet High-energy irradiation of liquid water and its solutes can transiently liberate electrons, which act as potent chemical reductants, but they are challenging to characterize precisely. Seeking to bridge the gap between liquid and gas, Elkins et al. (p. 1496 ) report results from photoelectron spectroscopy of hydrated electron dynamics in a liquid jet. The results reveal a very rapid transition from the electronic excited state to the ground state, prior to full relaxation of the solvent shell.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference40 articles.

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2. Theoretical Studies of Spectroscopy and Dynamics of Hydrated Electrons

3. Hydrated Interfacial Ions and Electrons

4. Dynamics of Solvated Electrons in Clusters

5. The hydrated electron: quantum simulation of structure, spectroscopy, and dynamics

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